Synthesis of Cu-(TAC) Composite with Oil Palm Empty Fruit Bunch Waste Activated Carbon Through the Adsorption Mechanism of βCarotene

Authors

  • Lidia Mutia Sari Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia
  • Jasmidi Jasmidi Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia
  • Hafni Indriati Nasution Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia
  • Moondra Zubir Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia
  • Siti Rahmah Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia
  • Rini Selly Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia
  • Putri Faradilla Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, 20221, Indonesia

DOI:

https://doi.org/10.24114/ijcst.v6i2.62305

Abstract

This study aims to determine the adsorption and desorption abilities of activated carbon and Cu-(TAC) composites in the β-carotene adsorption process on Crude Palm Oil (CPO). Oil Palm Empty Fruit Bunches (EFB) are used as activated carbon and modified with MOFs Cu-(TAC). Activated carbon and Cu-(TAC) composites were characterized by XRD, SEM-EDX, and BET. The concentration of β-carotene absorbed during the adsorption process was analyzed using a UV-Vis spectrophotometer. The variations used to determine the optimum conditions for absorption of β-carotene were the mass variation of the adsorbent and the variation in the contact time between the adsorbent and adsorbate. The results of the characterization of activated carbon showed a sharp absorption in the presence of O-H, C-H and C-O groups indicating the presence of cellulose. Activated carbon is amorphous and the Cu-(TAC) composite has a crystal structure and its pore size is mesoporous. The optimum conditions for the use of activated carbon for β-carotene adsorption were the mass variation of 8 grams with 0.495 ppm of β-carotene and contact time at 120 minutes with 2.605 ppm of β-carotene. The optimum condition of the Cu-(TAC) composite in the β-carotene adsorption process was at 4 gram mass variation with 1.026 ppm β-carotene content and optimum contact time at 60 minutes with 6.384 ppm β-carotene content. The ability of desorption can be seen from the percentage of desorption showing activated carbon in the 150th minute with 96.252% while in the Cu-(TAC) composite in the 30th minute with 88.188%.

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Published

2023-07-31

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Articles